Sharp AR-201 – страница 5

Date Issued: Nov. 1, 2000

MATERIAL SAFETY DATA SHEET

MSDS No. F-00991

Section 1. Product Identification

Product:

AR-201NT/T/FT/ST (Black Toner)

Section 2. Supplier’s Name and Address

Sharp Corporation

22-22 Nagaike-cho, Abeno-ku, Osaka, Japan

Local suppliers are listed below. Please contact the nearest supplier for additional information.

(Country) (Name and Telephone Number)

U.S.A. Sharp Electronics Corporation

Telephone number for information:1-800-237-4277

Emergency telephone number: 1-800-255-3924

Canada Sharp Electronics of Canada Ltd.

Telephone number for information:905-890-2100

Emergency telephone number: 1-800-255-3924

United Kingdom Sharp Electronics (U.K.) Ltd.

Telephone number for information:01923-474013

Section 3. Ingredients

Ingredients CAS No. Proportion OSHA PEL ACGIH TLV Other Limits

Styrene-Acrylate copolymer 29497-14-1 > 88 % Not listed Not listed None

3

3

Carbon black 1333-86-4 < 6.0% 3.5mg/m

3.5mg/m

None

Iron oxide 1309-38-2 < 4.5% Not listed Not listed None

3

3

Metal Complex dye 109125-51-1 < 1.5% 0.5mg/m

0.5mg/m

None

{

109125-50-0

84179-66-8

Section 4. Hazardous Identification (Emergency Overview)

Toner is a fine, black powder possessing no immediate hazard. There are no anticipated carcinogenic effects from

exposure based on animal tests performed using toner. When used as intended according to instructions, studies

do not indicate any symptoms of fibrosis will occur.

Section 5. Health Hazard Data

Route(s) of Entry:

Inhalation? Skin? Ingestion?

Yes No Possible but very unusual.

Health Hazards: Acute oral toxicity-------LDL0 of this toner is over 2,000mg/kg.

Mutagenicity-------------The result of Ames test is negative.

Carcinogenicity:In 1996 the IARC reevaluated carbon black as a Group 2B carcinogen (possible human

carcinogen). This classification is given to chemicals for which there is inadequate human

evidence, but sufficient animal evidence on which to base an opinion of carcinogenicity. The

classification is based upon the development of lung tumors in rats receiving chronic inhalation

exposures to free carbon black at levels that induce particle overload of the lung. Studies

performed in animal models other than rats did not show any association between carbon

black and lung tumors. Moreover, a two-year cancer bioassay using a typical toner preparation

containing carbon black demonstrated no association between toner exposure and tumor

development in rats.

Chronic Effect: In a study in rats of chronic inhalation exposure to a typical toner, a mild to moderate degree of

3

lung fibrosis was observed in 92% of the rats in the high concentration (16mg/m

) exposure

group, and a minimal to mild degree of fibrosis was noted in 22% of the animals in the middle

3

3

(4mg/m

) exposure group, but no pulmonary change was reported in the lowest (1mg/m

)

exposure group, the most relevant level to potential human exposures.

Signs and Symptoms of Exposure: Minimal irritation to respiratory tract may occur as with exposure to any

non-toxic dust.

Medical Conditions Generally Aggravated by Exposure: None

Emergency and First Aid Procedures:

Inhalation;Remove to fresh air. If effects occur, consult medical personnel.

Eye; In case of contact, immediately flush eyes with water for 15 minutes.

77

Section 6. Physical Chemical Characteristics

Boiling / Melting Point:Not applicable Specific Gravity: 1.1

Vapor Pressure: Not applicable Solubility in Water:Negligible

Vapor Density: Not applicable PH: Not applicable

Evaporation Rate: Not applicable Viscosity: Not applicable

Appearance: Fine powder Color: Black

Odor: Odorless

Section 7. Fire and Explosion Data

Flash Point (Method Used): Not applicable

Ignition Temperature: >350°C

Flammable Limits: (LEL); Not applicable (UEL); Not applicable

Extinguishing Media: CO2, dry chemical, foam or water

Special Fire Fighting Procedure: None

Unusual Fire and Explosion Hazard:This material has no unusual fire or explosion hazards.

Sensitivity to Mechanical Impact: None

Sensitivity to Static Charge: None

Section 8. Reactivity Data

Stability: Stable

Incompatibility (Material to Avoid): None

Hazardous Decomposition: CO and NOx

Hazardous Polymerization: Will not occur.

Section 9. Precautions for Safe Handling and Use

Personal Protection Information (Respiratory, Eye Protection and Protective Glove):

Use of a dust mask is recommended when handling a large quantity of toner or during long term

exposure, as with any non-toxic dust.

Engineering Control / Ventilation: Not required.

Work / Hygienic Practice: Inhalation should be minimized as with any non-toxic dust.

Steps to be taken in case of Spill or Leak: Sweep up or clean up with vacuum cleaner.

Waste Disposal Method: Waste material may be dumped or incinerated under conditions

which meet all federal, state and local environmental regulations.

Section 10.Regulatory Information

NFPA Rating (U.S.A.): Health = 1 Flammability = 1 Reactivity = 0

WHMIS Legislation (Canada): This product is not a controlled product.

Transport Information: This product is not a hazardous material.

UN No.: None allocated.

Section 11.Other Information

References:IARC (1996) IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans,

Vol. 65, Printing Process and Printing inks, Carbon Black and Some Nitro Compounds, Lyon, pp-

149-261

H. Muhle, B. Bellmann, O. Creutzenberg, C. Dasenbrock, H. Ernst, R. Kilpper, J. C. MacKenzie,

P. Morrow, U. Mohr, S. Takenaka, and R. Mermelstein (1991) Pulmonary Response to Toner upon

Chronic Inhalation Exposure in Rats. Fundamental and Applied Toxicology 17, pp. 280-299

78

Date Issued: Nov. 1, 2000

MATERIAL SAFETY DATA SHEET

MSDS No. F-30991

Section 1. Product Identification

Product

AR-201ND/DV/SD (Black Developer)

Section 2. Supplier’s Name and Address

Sharp Corporation

22-22 Nagaike-cho, Abeno-ku, Osaka, Japan

Local suppliers are listed below. Please contact the nearest supplier for additional information.

(Country) (Name and Telephone Number)

U.S.A. Sharp Electronics Corporation

Telephone number for information:1-800-237-4277

Emergency telephone number: 1-800-255-3924

Canada Sharp Electronics of Canada Ltd.

Telephone number for information:905-890-2100

Emergency telephone number: 1-800-255-3924

United Kingdom Sharp Electronics (U.K.) Ltd.

Telephone number for information:01923-474013

Section 3. Ingredients

Ingredients CAS No. Proportion OSHA PEL ACGIH TLV Other Limits

Iron powder 7439-89-6 > 92.5% Not listed Not listed None

Styrene-Acrylate copolymer 29497-14-1 < 7.0% Not listed Not listed None

3

3

Carbon black 1333-86-4 < 0.5% 3.5mg/m

3.5mg/m

None

Section 4. Hazardous Identification (Emergency Overview)

Developer is a black powder containing small amounts of toner, and possessing no immediate hazard.

There are no anticipated carcinogenic effects from exposure based on animal tests performed using toner.

Section 5. Health Hazard Data

Route(s) of Entry:

Inhalation? Skin? Ingestion?

No No Possible but very unusual.

Health Hazards: Acute oral toxicity------------LDL0 of this toner which is included in this developer is over

2,000mg/kg.

Mutagenicity------------------The toner, which is included in this developer, has been tested on

Ames test. The result is negative.

Carcinogenicity:In 1996 the IARC reevaluated carbon black as a Group 2B carcinogen (possible human

carcinogen). This classification is given to chemicals for which there is inadequate human

evidence, but sufficient animal evidence on which to base an opinion of carcinogenicity. The

classification is based upon the development of lung tumors in rats receiving chronic inhalation

exposures to free carbon black at levels that induce particle overload of the lung. Studies

performed in animal models other than rats did not show any association between carbon

black and lung tumors.

While there have been no studies to date using developer, a two-year cancer bioassay using a

typical toner preparation containing carbon black (a small amount of toner is included in the

developer mixture) demonstrated no association between toner exposure and tumor

development in rats.

Signs and Symptoms of Exposure: Minimal irritation to respiratory tract may occur as with exposure to any

non-toxic dust.

Medical Conditions Generally Aggravated by Exposure: None

Emergency and First Aid Procedures:

Inhalation;Remove to fresh air. If effects occur, consult medical personnel.

Eye; In case of contact, immediately flush eyes with water for 15 minutes.

79

Section 6. Physical Chemical Characteristics

Boiling / Melting Point:Not applicable Specific Gravity: about 7.3

Vapor Pressure: Not applicable Solubility in Water:Negligible

Vapor Density: Not applicable PH: Not applicable

Evaporation Rate: Not applicable Viscosity: Not applicable

Appearance: Fine powder Color: Black

Odor: Odorless

Section 7. Fire and Explosion Data

Flash Point (Method Used): Not applicable

Ignition Temperature: >350°C

Flammable Limits: (LEL); Not applicable (UEL); Not applicable

Extinguishing Media: CO2, dry chemical, foam or water

Special Fire Fighting Procedure: None

Unusual Fire and Explosion Hazard:This material has no unusual fire or explosion hazards.

Sensitivity to Mechanical Impact: None

Sensitivity to Static Charge: None

Section 8. Reactivity Data

Stability: Stable

Incompatibility (Material to Avoid): None

Hazardous Decomposition: CO and NOx

Hazardous Polymerization: Will not occur.

Section 9. Precautions for Safe Handling and Use

Personal Protection Information (Respiratory, Eye Protection and Protective Glove):

None required under normal use.

Engineering Control / Ventilation: Not required.

Work / Hygienic Practice: Not required.

Steps to be taken in case of Spill or Leak: Sweep up or clean up with vacuum cleaner.

Waste Disposal Method: Waste material may be dumped or incinerated under conditions

which meet all federal, state and local environmental regulations.

Section 10.Regulatory Information

NFPA Rating (U.S.A.): Health = 1 Flammability = 1 Reactivity = 0

WHMIS Legislation (Canada): This product is not a controlled product.

Transport Information: This product is not a hazardous material.

UN No.: None allocated.

Section 11.Other Information

References:IARC (1996) IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans,

Vol. 65, Printing Process and Printing inks, Carbon Black and Some Nitro Compounds, Lyon, pp-

149-261

H. Muhle, B. Bellmann, O. Creutzenberg, C. Dasenbrock, H. Ernst, R. Kilpper, J. C. MacKenzie, P.

Morrow, U. Mohr, S. Takenaka, and R. Mermelstein (1991) Pulmonary Response to Toner upon

Chronic Inhalation Exposure in Rats. Fundamental and Applied Toxicology 17, pp. 280-299

80

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VAROITUS!

CLASS 1 LASER PRODUCT

LAITTEEN KÄYTTÄMINEN

MUULLA KUIN TÄSSÄ

LASER KLASSE 1

KÄYTTÖOHJEESSA MAINITULLA

TAVALLA SAATTAA ALTISTAA

KÄYTTÄJÄN

LUOKAN 1 LASERLAITE

TURVALLISUUSLUOKAN 1

YLITTÄVÄLLE

NÄKYMÄTTÖMÄLLE

KLASS 1 LASERAPPARAT

LASERSÄTEILYLLE.

VARNING

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OM APPARATEN ANVÄNDS PÅ

1 ÊËÀÑÑÀ

ANNAT SÄTT ÄN I DENNA

BRUKSANVISNING

SPECIFICERATS, KAN

ANVÄNDAREN UTSÄTTAS FÖR

OSYNLIG LASERSTRÅLNING,

SOM ÖVERSKRIDER GRÄNSEN

FÖR LASERKLASS 1.

INVISIBLE LASER RADIATION WHEN OPEN AND INTERLOCKS DEFEATED.

USYNLIG LASERSTRÅLING NÅR DEKSEL ÅPNES OG SIKKERHEDSLÅS BRYTES.

CAUTION

AVOID EXPOSURE TO BEAM.

ADVERSEL

UNNGÅ EKSPONERING FOR STRÅLEN.

UNSICHTBARE LASERSTRAHLUNG WENN ABDECKUNG GEÖFFNET UND

OSYNLIG LASERSTRÅLNING NÄR DENNA DEL ÄR ÖPPNAD OCH SPÄRRAR ÄR

Laserstrahl

VORSICHT

SICHERHEITSVERRIEGELUNG ÜBERERÜCKT. NICHT DEM STRAHL AUSSETZEN.

VARNING

URKOPPLADE. STRÅLEN ÄR FARLIG. BETRAKTA EJ STRÅLEN.

USYNLIG LASERSTRÅLING VED ÅBNING, NÅR SIKKERHEDSAFBRYDERE ER

AVATTAESSA JA SUOJALUKITUS OHITETTAESSA OLET ALTTIINA NÄKYMÄTÖNTÄ

ADVARSEL

UDE AF FUNKTION. UNDGA UDSAETTELSE FOR STRÅLING.

VARO!

LASERSÄTEILYLLE. ÄLÄ KATSO SÄTEESEEN.

CLASS 1

LASER PRODUCT

ËÀÇÅÐÍÎÅ ÈÇÄÅËÈÅ

LASER KLASSE 1

1 ÊËÀÑÑÀ

AR-206

SHARP CORPORATION

PRINTED IN CHINA

2001A

KS

TINSE0456QSZZ